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This study develops mild, visible-light-mediated reversible deactivation radical polymerization (RDRP) methods to achieve controlled synthesis of fluoropolymers with narrow dispersity, tunable architectures, and specific sequences. The approach enables the preparation of high-performance solid electrolytes, ultra-high molecular weight polymers, and structured nanomaterials, while integration with flow chemistry and machine learning offers efficient and predictive routes for advanced fluoropolymer design.

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Photo-Controlled Polymerization Toward Well-Defined Fluoropolymers

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  • 发表日期：

    2026年

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  • Mao Chen

摘要

This study develops mild, visible-light-mediated reversible deactivation radical polymerization (RDRP) methods to achieve controlled synthesis of fluoropolymers with narrow dispersity, tunable architectures, and specific sequences. The approach enables the preparation of high-performance solid electrolytes, ultra-high molecular weight polymers, and structured nanomaterials, while integration with flow chemistry and machine learning offers efficient and predictive routes for advanced fluoropolymer design.