The research focused on Williamson nonlinear governing flow on electrical Magneto hydrodynamic incompressible, steady fluid over a porous stretching sheet in a two-dimensional direction. The permeable stretching sheet embedded by Williamson fluid based on the flow model of non-Darcy Forchheimer law with higher order chemical reaction. The energy equation is dominated by the dissipation parameter. The governing mathematical partial derivative formulations are changed to a system of ordinary differential formulations with appropriate similarity transformation. The mathematical formulations are evaluated employing the numerical method of R-K fourth-order scheme. MATLAB software bvp4c is used for computing numerical results. The impact of emerging dimensionless quantifiers such as Williamson number, porous, electric, thermophoresis, Brownian motion, Prandtl, Schmidt dimensionless number, Eckert number, Hartmann number, and chemical reaction quantifiers are investigated in detail.