At present, the main methods of growing Gallium Nitride (GaN) single crystal substrates include High-nitrogen-pressure solution growth (HNPSG), Na-flux method (Na Flux), Hydride vapor phase epitaxy (HVPE) and Ammonothermal method. HNPSG has stringent requirements for equipment (pressure greater than 1 Gpa, temperature greater than 1500 °C, making the production of large-sized crystals and industrialization challenging. The remaining three methods have their own advantages and disadvantages: HVPE has a rapid growth rate and is easy to obtain large-size crystal, which is the most promising method for commercial applications.

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Ammonothermal Method

  • Ke Xu,
  • Jianfeng Wang,
  • Guoqiang Ren,
  • Zongliang Liu

摘要

At present, the main methods of growing Gallium Nitride (GaN) single crystal substrates include High-nitrogen-pressure solution growth (HNPSG), Na-flux method (Na Flux), Hydride vapor phase epitaxy (HVPE) and Ammonothermal method. HNPSG has stringent requirements for equipment (pressure greater than 1 Gpa, temperature greater than 1500 °C, making the production of large-sized crystals and industrialization challenging. The remaining three methods have their own advantages and disadvantages: HVPE has a rapid growth rate and is easy to obtain large-size crystal, which is the most promising method for commercial applications.