Black liquor is an invaluable resource for paper mills, processed through various unit operations in the chemical recovery systems to recover and recycle pulping chemicals, and efficiently generate steam and electrical power. During its processing in the chemical recovery systems, black liquor undergoes four major unit operations: concentration, combustion, causticization, and calcination. These operations present significant challenges to mills, requiring careful black liquor management to ensure efficient chemical recovery and energy generation. The properties of black liquor are crucial in understanding the key characteristics that affect the operations of chemical recovery systems. These properties depend on various factors such as raw materials and cooking conditions, including chemical charge, time, temperature, and pressure. Analysis of black liquor properties helps to reveal its nature and aids plant managers and engineers in operating chemical recovery processes smoothly and efficiently. Black liquor properties can be categorized into three main subcategories: chemical, physical and rheological and combustion properties. Since the chemical recovery unit operations in mills differ in their level of operation, equipment design, automation, and controls, therefore, a better understanding of black liquor properties supports to understand their impact in efficient operation of processes. Thus, insight in the black liquor properties becomes crucial for process engineers and operators to recognize their intricate relationships with processes, allowing them to strike an optimal balance for efficient operation of chemical recovery systems.