The surface active agent (surfactant) had shown promising impacts on the physico-chemical properties due to their molecular architecture designed. Ninhydrin (Nin) is known as a universally color-emerging compound. Nin reactions are also significant to carry out in Gemini/mixed micellar system and should be made an effort to get the improved results. The theory recognized here could be advantageous in developing visualization of Nin-improved fingerprints, in forensic research and bio-analytical work. The consequences in mixed micelles may resolve the catalytic issues that occurred in catalysis and related research investigations. However, notwithstanding of a massive data being available on the physico-chemical studies of Geminis and their mixed systems, interpretation of the amine-functional group with Nin is very infrequent in the presence of Gemini/mixed surfactants and it further requires an advanced development.