The interaction of orbitals and their impact on conformations and reactivity influences the chemo-, regio-, and stereoselectivity of organic reactions. In addition to the anomeric effect and allylic strain, cyclizations and the acidity of organic compounds are also addressed.

错误:搜索内容不能为空,请输入英文关键词
错误:关键词超出字数限制,请精简
高级检索

Stereoelectronic Effects

  • Alexander Düfert

摘要

The interaction of orbitals and their impact on conformations and reactivity influences the chemo-, regio-, and stereoselectivity of organic reactions. In addition to the anomeric effect and allylic strain, cyclizations and the acidity of organic compounds are also addressed.