The rapid advancement of the Internet of Things (IoT) and Artificial Intelligence (AI) has transformed traditional educational paradigms, paving the way for smart classrooms and personalized learning experiences. This paper explores the critical role of IoT and AI technologies in enhancing foundational thinking skills—such as critical thinking, problem-solving, and adaptive learning—in students, aligning with the objectives of sustainable development. By integrating intelligent sensors, data analytics, and machine learning, smart learning environments can provide real-time insights into student engagement, learning patterns, and cognitive development. These technologies not only optimize classroom interactions but also promote equitable access to quality education, empowering learners to become innovative thinkers prepared for global challenges. Furthermore, the paper discusses the implications of IoT and AI in addressing educational disparities and fostering inclusive learning ecosystems. Through a synthesis of current research, case studies, and practical implementations, this study presents a framework for leveraging smart technologies to build resilient educational infrastructures that support sustainable development goals.