The principal objective of this work is to study the steam condensation process influenced by varying surface morphology created on a copper substrate by the deposition of microparticles using thermal spray coating technique. A copper substrate is coated with microparticles of tungsten carbide and aluminium oxide. The surface characteristics of both the untreated and coated samples were analyzed using a stylus profilometer, SEM, and EDX. Film condensation experiments were then conducted on both the untreated copper plate and the coated samples. The results demonstrate that surfaces with varying morphologies show a significant difference in condensation heat transfer performance. Specifically, the copper substrate coated with aluminium oxide microparticles exhibited a 120% improvement in condensation performance compared to the untreated surface.