Reactive aluminum (Al) alloy powders are promising for advanced manufacturing, joining, and energetic applications, yet scalable routes that couple controlled reactivity with safe handling remain limited. While nanoscale Al powders ignite readily, their agglomeration, handling, and safety limit broad deployment. Here, we manufacture micron-sized Al-based powders produced by ultrasonic atomizationUltrasonic atomization (UA), targeting a balance of enhanced reactivity and process robustness. Binary systems (Al–Cu, Al–Si, Al–Mg) and pure Al were synthesized, and their morphology, phases present, thermal stability, and oxidation behaviorOxidation behavior were characterized using XRD, SEM, and DSC/TGA in an Ar+ \({\text {O}}_{2}\) environment. We show that alloy selection and UA-controlled microstructure can modify the native \({\text {Al}}_{2}{\text {O}}_{3}\) passivation, alter oxidation pathways, and shift thermal onsets/exotherms. The results establish a manufacturing-forward framework for designing micron-sized powders with tunable ignition/oxidation behaviorOxidation behavior.

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Synthesis and Characterization of Ultrasonically Atomized Al-Based Alloy Powders for Tunable Thermal Reactivity

  • Chetan Singh,
  • Ava Goglia,
  • Peter Mastracco,
  • Michael Flickinger,
  • Laszlo J. Kecskes,
  • Paulette Clancy,
  • Timothy P. Weihs

摘要

Reactive aluminum (Al) alloy powders are promising for advanced manufacturing, joining, and energetic applications, yet scalable routes that couple controlled reactivity with safe handling remain limited. While nanoscale Al powders ignite readily, their agglomeration, handling, and safety limit broad deployment. Here, we manufacture micron-sized Al-based powders produced by ultrasonic atomizationUltrasonic atomization (UA), targeting a balance of enhanced reactivity and process robustness. Binary systems (Al–Cu, Al–Si, Al–Mg) and pure Al were synthesized, and their morphology, phases present, thermal stability, and oxidation behaviorOxidation behavior were characterized using XRD, SEM, and DSC/TGA in an Ar+ \({\text {O}}_{2}\) environment. We show that alloy selection and UA-controlled microstructure can modify the native \({\text {Al}}_{2}{\text {O}}_{3}\) passivation, alter oxidation pathways, and shift thermal onsets/exotherms. The results establish a manufacturing-forward framework for designing micron-sized powders with tunable ignition/oxidation behaviorOxidation behavior.