Self-supervised learning (SSL) models such as Wav2Vec 2.0 and HuBERT have shown remarkable success in extracting phonetic information from raw audio without labelled data. While prior work has demonstrated that SSL embeddings encode phonetic features at the frame level, it remains unclear whether these models preserve temporal structure, specifically, whether embeddings at phoneme boundaries reflect the identity and order of adjacent phonemes. This study investigates the extent to which boundary-sensitive embeddings from HubertSoft, a soft-clustering variant of HuBERT, encode phoneme transitions. Using the CORPRES Russian speech corpus, we labelled 20 ms embedding windows with triplets of phonemes corresponding to their start, centre, and end segments. A neural network was trained to predict these positions separately, and multiple evaluation metrics, such as ordered, unordered accuracy and a flexible centre accuracy, were used to assess temporal sensitivity. Results show that the model achieves up to 53% ordered accuracy, indicating strong temporal awareness, while unordered accuracy exceeds 90%, confirming robust phonetic content encoding. Confusion patterns further suggest that the model encodes articulatory detail and coarticulatory effects. These findings contribute to our understanding of the internal structure of SSL speech representations and their potential for phonological analysis and fine-grained transcription tasks.