This book chapter explores the transformative potential of psychedelic-assisted couple therapy, a novel technique that blends the dynamics of love connections with the therapeutic benefits of psychedelics. The chapter presents an extensive examination of the theoretical underpinnings, therapeutic approaches, and ethical issues related to this developing discipline, drawing on the most recent research and clinical experiences. The chapter’s main section examines the therapeutic process, highlighting the significance of preparation, intention, and setting for individuals as well as couples. It explores the nature of the intense psychedelic experience itself, talking about how it may improve introspection, empathy, and emotional connectedness. The important role that trained therapists play in supporting vulnerable, open communication, and trust in couples as they travel through these life-changing experiences is highlighted.