Human resource strategies are prominent in ensuring employee performance and operational effectiveness in corporate companies. In the realm of business, the Environmental, Social, and Governance (ESG) framework serves as a catalyst for the promotion of sustainability. Business strategies, day to day practices, its model, and core policy can only be fruitful once employees are ready to understand and imbibe its essence in them. In this chapter, the researchers aim to explore and highlight the critical facets linked to ESG-driven HRM practices and corporate performance. The findings will have greater significance for HR policymakers and regulatory bodies, which can formulate specific policies in the HRM domain linked to long-term corporate performance. Present Chapter explore various prominent discussion on green practices in HRM area which directly and indirectly adhere to a sound corporate performance. It also exclusively offers imperatives for corporate and business level managers to draw attention on SDG, ESG and Green HRM practices which has manifold positive outcomes.