Palladium-catalyzed cross-coupling reaction of organosilicons with organic halides, triflates, etc. In the presence of an activating agent such as fluoride or hydroxide (transmetalation is reluctant to occur without the effect of an activating agent). For the catalytic cycle, see the Kumada coupling.

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Hiyama Reaction

  • Jie Jack Li

摘要

Palladium-catalyzed cross-coupling reaction of organosilicons with organic halides, triflates, etc. In the presence of an activating agent such as fluoride or hydroxide (transmetalation is reluctant to occur without the effect of an activating agent). For the catalytic cycle, see the Kumada coupling.