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Carbocation rearrangement of primary amines via diazotization to give alcohols through C–C bond migration. The Demjanov rearrangement has been largely replaced by the Tiffeneau–Demjanov rearrangement due to the latter′s convenience.

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Demjanov Rearrangement

  • 章节

  • 发表日期：

    2026年

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  • Jie Jack Li

摘要

Carbocation rearrangement of primary amines via diazotization to give alcohols through C–C bond migration. The Demjanov rearrangement has been largely replaced by the Tiffeneau–Demjanov rearrangement due to the latter′s convenience.