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The isomerization of secondary and tertiary α-acetylenic alcohols to α,β-unsaturated carbonyl compounds via 1,3-shift. When the acetylenic group is terminal, the products are aldehydes, whereas the internal acetylenes give ketones.

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Meyer–Schuster Rearrangement

  • 章节

  • 发表日期：

    2026年

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  • Jie Jack Li

摘要

The isomerization of secondary and tertiary α-acetylenic alcohols to α,β-unsaturated carbonyl compounds via 1,3-shift. When the acetylenic group is terminal, the products are aldehydes, whereas the internal acetylenes give ketones.