The demand for pure uranium compounds for various applications in the defense and power sectors is continually rising. Consequently, this study investigates the processing of an indigenous uranium ore containing albite (Na2.00Al2.00Si6.00O16.00), boltwoodite (Na2.00K2.77U3.00Si6.00O9.00H4.00), thorite (Th4.00Si4.00O16.00), and quartz (Si6.00O6.00) in a sodium carbonate medium to obtain uranylUranyl pregnant leach solutionPregnant leach solution (UPLS). The experimental test parameters such as lixiviant concentration, reaction temperature, and particle size on the extent of uranium ore dissolution were investigated for optimal uranium extractionUranium extraction conditions. At established leaching conditions (2.5 mol/L Na2CO3, 75 °C, 75 µm), an 82.5% dissolution rate was achieved within 120 min of retention time. The estimatedActivation energy activation energyEnergy (Ea) of 43.44 kJ/mol affirms an eco-feasible chemical mechanism for optimal uranium extractionUranium extraction. Thus, the UPLS obtained was subsequently treated and beneficiated to produce an industrially acceptable uranium compound for defined domestic and industrial uses.

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Eco-Feasible Energy Approach for Industrial Uranium Compound Preparation Using Uranyl Pregnant Leach Solution (UPLS)

  • Alafara A. Baba,
  • Mustapha A. Raji,
  • Christianah O. Adeyemi,
  • Kuranga I. Ayinla,
  • Jude O. Majasan,
  • Rasheed O. Agava

摘要

The demand for pure uranium compounds for various applications in the defense and power sectors is continually rising. Consequently, this study investigates the processing of an indigenous uranium ore containing albite (Na2.00Al2.00Si6.00O16.00), boltwoodite (Na2.00K2.77U3.00Si6.00O9.00H4.00), thorite (Th4.00Si4.00O16.00), and quartz (Si6.00O6.00) in a sodium carbonate medium to obtain uranylUranyl pregnant leach solutionPregnant leach solution (UPLS). The experimental test parameters such as lixiviant concentration, reaction temperature, and particle size on the extent of uranium ore dissolution were investigated for optimal uranium extractionUranium extraction conditions. At established leaching conditions (2.5 mol/L Na2CO3, 75 °C, 75 µm), an 82.5% dissolution rate was achieved within 120 min of retention time. The estimatedActivation energy activation energyEnergy (Ea) of 43.44 kJ/mol affirms an eco-feasible chemical mechanism for optimal uranium extractionUranium extraction. Thus, the UPLS obtained was subsequently treated and beneficiated to produce an industrially acceptable uranium compound for defined domestic and industrial uses.