In this work, we explore the application of Enterprise Architecture (EA) frameworks, specifically TOGAF and ArchiMate, to model the alignment between socio-political artifacts and technological artifacts within Decentralised Autonomous Organisations (DAOs). DAOs are new organisation model that leverages blockchain (BC) technology to implement decentralised governance such as Liquid Democracy (LD) which respect anarchist principles. However, the challenge lies in demonstrating the traceability between socio-political governance processes and the technological artifacts that enables these processes. This paper addresses this gap by applying Design Science Research (DSR) methodology to develop a reference architecture. This Architecture serves as a structured model to analyze and verify the alignment of decentralised governance processes with their technological implementations DAOs. This work contribution is a systematic approach to modelisation and analysis of socio-political structures of decentralised organisations, ensuring they align with the underlying technology supporting them.