Abstract <p>The effect of the initial size of alumina particles on the density, microstructure, hardness, and fracture toughness of ceramics obtained by conventional and spark plasma sintering (SPS) has been studied. We studied ceramics obtained from commercial Al<sub>2</sub>O<sub>3</sub> powders with an initial particle size of 40 to 50 nm, 0.2 μm, and 1 μm and domestic fine powders with an initial particle size of 0.2 to 3 mm, and Al<sub>2</sub>O<sub>3</sub> + 0.25 vol % MgO and Al<sub>2</sub>O<sub>3</sub> + 10 vol % ZrO<sub>2</sub>. It is shown that the density of alumina ceramics nonmonotonically depends on the initial size of Al<sub>2</sub>O<sub>3</sub> powder particles. It has been established that an increase in the grain size leads to a nonmonotonic change in the hardness of alumina ceramics. It has been established that the addition of 0.25 vol % MgO accelerates the sintering of alumina. The addition of 10 vol % ZrO<sub>2</sub> makes it possible to provide an optimal combination of hardness and fracture toughness. It is shown that fine-grained ceramics obtained by the SPS method have a higher hardness. It has been suggested that SPS of submicron alumina powders with an amorphous layer on the surface, additionally stabilized by zirconia particles, is promising for further increasing the hardness of alumina ceramics.</p>

错误:搜索内容不能为空,请输入英文关键词
错误:关键词超出字数限制,请精简
高级检索

Comparative Analysis of the Structure and Properties of Alumina Ceramics Obtained by Conventional Pressureless Sintering and Spark Plasma Sintering

  • M. S. Boldin,
  • D. A. Tikhonova,
  • A. D. Borkova,
  • S. I. Udachin,
  • E. A. Lantsev,
  • A. V. Voronin,
  • A. A. Murashov,
  • O. A. Belkin,
  • A. V. Nokhrin,
  • V. N. Chuvil’deev

摘要

Abstract

The effect of the initial size of alumina particles on the density, microstructure, hardness, and fracture toughness of ceramics obtained by conventional and spark plasma sintering (SPS) has been studied. We studied ceramics obtained from commercial Al2O3 powders with an initial particle size of 40 to 50 nm, 0.2 μm, and 1 μm and domestic fine powders with an initial particle size of 0.2 to 3 mm, and Al2O3 + 0.25 vol % MgO and Al2O3 + 10 vol % ZrO2. It is shown that the density of alumina ceramics nonmonotonically depends on the initial size of Al2O3 powder particles. It has been established that an increase in the grain size leads to a nonmonotonic change in the hardness of alumina ceramics. It has been established that the addition of 0.25 vol % MgO accelerates the sintering of alumina. The addition of 10 vol % ZrO2 makes it possible to provide an optimal combination of hardness and fracture toughness. It is shown that fine-grained ceramics obtained by the SPS method have a higher hardness. It has been suggested that SPS of submicron alumina powders with an amorphous layer on the surface, additionally stabilized by zirconia particles, is promising for further increasing the hardness of alumina ceramics.