Abstract <p>The results of studies of the effect of metals on the physicochemical and physicomechanical properties of polyacrylates based on the analysis of the energy characteristics of the polymer are generalized. For this purpose, the effect of introduced into a polymer composition highly dispersed metal/metal-containing inorganic fillers on the relaxation behavior of the polymers is studied. An analysis of the properties of polyacrylates with different elasticities in the presence of a metal was performed based on the internal friction spectra and temperature–frequency dependences of the oscillatory process of a composite that are obtained using dynamic relaxation spectroscopy based on the determination of the temperature regions of materialization of the elastic properties of a composite at –150 to 100°C. The results of studies of the effect of metal powders of iron and zinc and zinc oxide on the physicochemical and physicomechanical properties of acrylic elastomers are presented and generalized versus an unfilled polymer.</p>

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The Effect of the Surface of a Metal on the Physicochemical and Physicomechanical Properties of Latex Polyacrylates. 1. Polymer Compositions

  • T. R. Aslamazova,
  • V. A. Kotenev,
  • V. A. Lomovskoi

摘要

Abstract

The results of studies of the effect of metals on the physicochemical and physicomechanical properties of polyacrylates based on the analysis of the energy characteristics of the polymer are generalized. For this purpose, the effect of introduced into a polymer composition highly dispersed metal/metal-containing inorganic fillers on the relaxation behavior of the polymers is studied. An analysis of the properties of polyacrylates with different elasticities in the presence of a metal was performed based on the internal friction spectra and temperature–frequency dependences of the oscillatory process of a composite that are obtained using dynamic relaxation spectroscopy based on the determination of the temperature regions of materialization of the elastic properties of a composite at –150 to 100°C. The results of studies of the effect of metal powders of iron and zinc and zinc oxide on the physicochemical and physicomechanical properties of acrylic elastomers are presented and generalized versus an unfilled polymer.