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Abstract <p>The properties of supported pelletized (Pt/Ce<sub>0.75</sub>Zr<sub>0.25</sub>O<sub>2</sub>) and structured monolithic platinum catalysts (Pt/Ce<sub>0.75</sub>Zr<sub>0.25</sub>O<sub>2</sub>/η‑Al<sub>2</sub>O<sub>3</sub>/FeCrAl) for methanol steam reforming to synthesis gas for feeding solid oxide fuel cells have been studied and compared. Comparative studies show that the active Pt/Ce<sub>0.75</sub>Zr<sub>0.25</sub>O<sub>2</sub> system is more efficient on a structured monolithic support. In particular, at atmospheric pressure, a temperature of 400°C, and a reaction mixture (30 vol % CH<sub>3</sub>OH, 35 vol % H<sub>2</sub>O, 35 vol % N<sub>2</sub>) weight hourly space velocity of 60 L/(g<sub>cat</sub> h), the 0.15 wt % Pt/8 wt % Ce<sub>0.75</sub>Zr<sub>0.25</sub>O<sub>2</sub>/6 wt % η-Al<sub>2</sub>O<sub>3</sub>/FeCrAl catalyst provides a complete methanol conversion to synthesis gas with a total H<sub>2</sub> and CO content of ~60 vol % and a productivity with respect to synthesis gas of ~85 L(H<sub>2</sub> + CO)/(g<sub>cat</sub> h).</p>

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Methanol Steam Reforming to a Hydrogen-Containing Gas in the Presence of Supported Platinum Catalysts

  • 期刊论文

  • 发表日期：

    2026年3月1日

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  • A. D. Kuznetsova,
  • V. N. Rogozhnikov,
  • P. V. Snytnikov,
  • S. D. Badmaev

摘要

Abstract

The properties of supported pelletized (Pt/Ce0.75Zr0.25O2) and structured monolithic platinum catalysts (Pt/Ce0.75Zr0.25O2/η‑Al2O3/FeCrAl) for methanol steam reforming to synthesis gas for feeding solid oxide fuel cells have been studied and compared. Comparative studies show that the active Pt/Ce0.75Zr0.25O2 system is more efficient on a structured monolithic support. In particular, at atmospheric pressure, a temperature of 400°C, and a reaction mixture (30 vol % CH3OH, 35 vol % H2O, 35 vol % N2) weight hourly space velocity of 60 L/(gcat h), the 0.15 wt % Pt/8 wt % Ce0.75Zr0.25O2/6 wt % η-Al2O3/FeCrAl catalyst provides a complete methanol conversion to synthesis gas with a total H2 and CO content of ~60 vol % and a productivity with respect to synthesis gas of ~85 L(H2 + CO)/(gcat h).