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Abstract <p>The main laws and routes of the liquid-phase hydrogenation and isomerization of carbocyclic alkenes and dienes of the norbornene series in the presence of heterogeneous catalysts were systematized, and the reaction mechanisms were discussed. The reaction products were identified and the material balance was studied. Conditions for the hydrogenation and isomerization of the compounds were selected such as to provide the preservation of the norbornane framework. The reactivity of multiple bonds in norbornenes was assessed by experimental and quantum chemical methods. Adequate kinetic models of the processes in terms of the Langmuir–Hinshelwood approach and in the representation of multiple adsorption of substrates on a single active site were developed.</p>

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Heterogeneous Hydrogenation and Isomerization of Carbocyclic Compounds of the Norbornene Series: A Review

  • 期刊论文

  • 发表日期：

    2025年6月24日

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  • V. V. Zamalyutin,
  • E. V. Okuneva,
  • S. S. Moskvichev,
  • V. R. Flid

摘要

Abstract

The main laws and routes of the liquid-phase hydrogenation and isomerization of carbocyclic alkenes and dienes of the norbornene series in the presence of heterogeneous catalysts were systematized, and the reaction mechanisms were discussed. The reaction products were identified and the material balance was studied. Conditions for the hydrogenation and isomerization of the compounds were selected such as to provide the preservation of the norbornane framework. The reactivity of multiple bonds in norbornenes was assessed by experimental and quantum chemical methods. Adequate kinetic models of the processes in terms of the Langmuir–Hinshelwood approach and in the representation of multiple adsorption of substrates on a single active site were developed.