Scholarlink

Abstract <p>This work presents the results on the synthesis of new monomers based on 1,1-bis(4-hydroxyphenyl)-2,2-dichloroethene or 1,1-bis(3,5-dibromo-4-hydroxyphenyl)-2,2-dichloroethene and 1,1-di(4-chlorophenyl)-2,2-dichloroethene dihalide. Using these monomers and 4,4′-difluoro diphenyl ketone, halogen-containing unsaturated poly(arylene ether ketones) are prepared by the nucleophilic substitution reaction in <i>N</i>,<i>N</i>-dimethylacetamide. The structure and basic properties of the synthesized poly(arylene ether ketones) are investigated. The composition and structure of the polymer materials are studied by IR spectroscopy, X-ray diffraction analysis, and differential scanning calorimetry. It is shown that poly(arylene ether ketones) are amorphous and well soluble in aliphatic and amide solvents and have good moisture, heat, and fire resistance. Due to high mechanical characteristics these poly(arylene ether ketones) can be recommended as heat-resistant structural polymer materials.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Poly(arylene ether ketones) with Dichloroethylene Groups

  • 期刊论文

  • 发表日期：

    2025年6月1日

查看全文
  • A. M. Kharaev,
  • R. Ch. Bazheva,
  • Z. L. Beslaneeva,
  • D. A. Alakaeva,
  • M. M. Parchieva,
  • M. A. Yalkhoroeva,
  • Z. I. Inarkieva

摘要

Abstract

This work presents the results on the synthesis of new monomers based on 1,1-bis(4-hydroxyphenyl)-2,2-dichloroethene or 1,1-bis(3,5-dibromo-4-hydroxyphenyl)-2,2-dichloroethene and 1,1-di(4-chlorophenyl)-2,2-dichloroethene dihalide. Using these monomers and 4,4′-difluoro diphenyl ketone, halogen-containing unsaturated poly(arylene ether ketones) are prepared by the nucleophilic substitution reaction in N,N-dimethylacetamide. The structure and basic properties of the synthesized poly(arylene ether ketones) are investigated. The composition and structure of the polymer materials are studied by IR spectroscopy, X-ray diffraction analysis, and differential scanning calorimetry. It is shown that poly(arylene ether ketones) are amorphous and well soluble in aliphatic and amide solvents and have good moisture, heat, and fire resistance. Due to high mechanical characteristics these poly(arylene ether ketones) can be recommended as heat-resistant structural polymer materials.