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Abstract <p>Oxidative cross-coupling of secondary phosphine chalcogenides with mercaptoalkanols in the presence of CCl<sub>4</sub>/Et<sub>3</sub>N at an equimolar reactant ratio under mild conditions (20–25°C, 2–7 h) afforded the corresponding <i>S</i>-hydroxyalkyl phosphinochalcogenothioates with high chemoselectivity in 76–89% isolated yield.</p>

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Chemoselective Oxidative Cross-Coupling of Secondary Phosphine Chalcogenides with Mercaptoalkanols: Synthesis of S-Hydroxyalkyl Phosphinochalcogenothioates

  • 期刊论文

  • 发表日期：

    2025年7月1日

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  • K. O. Khrapova,
  • P. A. Volkov,
  • A. A. Telezhkin,
  • L. I. Larina

摘要

Abstract

Oxidative cross-coupling of secondary phosphine chalcogenides with mercaptoalkanols in the presence of CCl4/Et3N at an equimolar reactant ratio under mild conditions (20–25°C, 2–7 h) afforded the corresponding S-hydroxyalkyl phosphinochalcogenothioates with high chemoselectivity in 76–89% isolated yield.