Abstract <p>Oxidative coupling of aromatic amines with 3-aryl-3-oxopropanenitriles in the presence of selenium(IV) oxide gave the corresponding 2-arylimino-3-oxopropanenitriles. Similar reactions of arylamines with propanedinitrile afforded 2-(arylimino)propanedinitriles.</p>

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Synthesis of Substituted 2-Arylimino-3-oxopropanenitriles and 2-(Arylimino)propanedinitriles by Oxidative Coupling of Primary Aromatic Amines with Aroylacetonitriles and Malononitrile

  • A. V. Kachanov,
  • M. A. Kucheshov,
  • O. Yu. Slabko

摘要

Abstract

Oxidative coupling of aromatic amines with 3-aryl-3-oxopropanenitriles in the presence of selenium(IV) oxide gave the corresponding 2-arylimino-3-oxopropanenitriles. Similar reactions of arylamines with propanedinitrile afforded 2-(arylimino)propanedinitriles.