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Abstract <p>Polycarboxylic diadamantylarenes have been synthesized by the double alkylation aromatic hydrocarbons with adamantane-1-carboxylic acids, 2-(adamantan-1-yl)acetic acids, and hydroxy-substituted mono- and dicarboxylic acids of the adamantane series under acidic conditions. The synthesized compounds can be regarded as structurally rigid polycarboxylate ligands for the design of metal–organic frameworks.</p>

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Synthesis of Polycarboxylic Diadamantylarenes

  • 期刊论文

  • 发表日期：

    2025年3月1日

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  • E. A. Ivleva,
  • D. V. Zvereva,
  • Yu. E. Khatmullina,
  • Yu. N. Klimochkin

摘要

Abstract

Polycarboxylic diadamantylarenes have been synthesized by the double alkylation aromatic hydrocarbons with adamantane-1-carboxylic acids, 2-(adamantan-1-yl)acetic acids, and hydroxy-substituted mono- and dicarboxylic acids of the adamantane series under acidic conditions. The synthesized compounds can be regarded as structurally rigid polycarboxylate ligands for the design of metal–organic frameworks.