Reduction of the Peroxide Products of Cyclooctene Ozonolysis with Sebacic Acid Dihydrazide
摘要
Abstract
The reduction with sebacic acid dihydrazide of the peroxide products of cyclooctene ozonolysis in different solvents leads, depending on the solvent, to three acyclic differently functionalized cyclooctene derivatives: methyl 11,20-dioxo-9,10,21,22-tetraazadocos-8E-enoic acid is formed in methanol, 11,20-dioxo-9,10,21,22-tetraazadocos-8E-enoic acid in methylene chloride, and natural cortic acid in THF.