Scholarlink

Abstract <p>Intramolecular asymmetric Heck reaction of sterically hindered 3-(adamantan-1-yl)-1-(2-bromophenyl)prop-2-en-1-one, catalyzed by a semicorrin nickel complex and a bisphosphine palladium complex, was studied. The nickel-containing catalytic system offers the advantage that it provides that the enantiomeric excess for the resulting 3-(adamantan-1-yl)indan-1-one of 97%.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Asymmetric Reductive Heck Cyclization of 3-(Adamantan-1-yl)-1-(2-bromophenyl)prop-2-en-1-one: Highly Enantioselective Synthesis of 3-(Adamantan-1-yl)indan-1-one

  • 期刊论文

  • 发表日期：

    2025年2月1日

查看全文
  • A. N. Reznikov,
  • S. Yu. Vostrukhina,
  • M. A. Ashatkina,
  • Yu. N. Klimochkin

摘要

Abstract

Intramolecular asymmetric Heck reaction of sterically hindered 3-(adamantan-1-yl)-1-(2-bromophenyl)prop-2-en-1-one, catalyzed by a semicorrin nickel complex and a bisphosphine palladium complex, was studied. The nickel-containing catalytic system offers the advantage that it provides that the enantiomeric excess for the resulting 3-(adamantan-1-yl)indan-1-one of 97%.