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Abstract <p>A novel binuclear manganese(II) coordination polymer [MnL(bpe)<sub>0.5</sub>]<sub><i>n</i></sub> was synthesized based on the hydrolysis product of anastrozole (H<sub>2</sub>L) and 1,2-di(4-pyridyl)ethylene (bpe) coligand under hydrothermal conditions. The structure of the Mn(II) CP was determined by single-crystal X-ray diffraction. The center Mn(II) adopts a distorted coordination configuration and is extended by L<sup>2–</sup> and bpe ligands to form a three-dimensional (3D) pillar-layer framework. The magnetic data shows the existence of dominant antiferromagnetic behavior within the binuclear Mn(II) CP.</p>

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Synthesis, Structure and Magnetic Property of a Novel Binuclear Manganese(II) Coordination Polymer Based on a Bifunctional Ligand

  • 期刊论文

  • 发表日期：

    2026年6月3日

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  • Hai-Xia Kang,
  • Feng-Yang Ju,
  • Yu-Qin Fu,
  • Guang-Zhen Liu

摘要

Abstract

A novel binuclear manganese(II) coordination polymer [MnL(bpe)0.5]n was synthesized based on the hydrolysis product of anastrozole (H2L) and 1,2-di(4-pyridyl)ethylene (bpe) coligand under hydrothermal conditions. The structure of the Mn(II) CP was determined by single-crystal X-ray diffraction. The center Mn(II) adopts a distorted coordination configuration and is extended by L2– and bpe ligands to form a three-dimensional (3D) pillar-layer framework. The magnetic data shows the existence of dominant antiferromagnetic behavior within the binuclear Mn(II) CP.