Abstract <p>Poled thin films of composite polymer materials based on PMMA doped with high thermally stable chromophores with the structure D-π-A1-π-A2 and D-π-A1A2 with a carbazole donor D, a quinoxalinone core, A1, either in a π-conjugated bridge or in a macroacceptor, were obtained. The effect of the chromophore structure on the values and long-term stability of the nonlinear optical coefficient, <i>d</i><sub>33</sub>, of such thin films has been shown.</p>

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Nonlinear Optical Properties of Composite Materials Based on Push-Pull Chromophores with Carbazole Donor and Quinoxalinone in π-Conjugated Bridge or in Macroacceptor

  • Alexander A. Tazin,
  • Alexey A. Kalinin,
  • Danil N. Petrov,
  • Sirina M. Sharipova,
  • Alfira A. Valieva,
  • Anastasiya V. Sharipova,
  • Alexey B. Dobrynin,
  • Tatyana A. Vakhonina,
  • Artemiy G. Shmelev,
  • Ayrat R. Khamatgalimov,
  • Marina Yu. Balakina

摘要

Abstract

Poled thin films of composite polymer materials based on PMMA doped with high thermally stable chromophores with the structure D-π-A1-π-A2 and D-π-A1A2 with a carbazole donor D, a quinoxalinone core, A1, either in a π-conjugated bridge or in a macroacceptor, were obtained. The effect of the chromophore structure on the values and long-term stability of the nonlinear optical coefficient, d33, of such thin films has been shown.