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Abstract <p>A series of macrocyclic ligands featuring pyridyl functionalization and a disulfide linkage, along with their corresponding ruthenium(II) and osmium(II) complexes, were synthesized and characterized. The monodentate complexes were investigated in both the ‘open’ and ‘closed’ forms. These studies on electron/energy transfer through disulfide linkages provide critical insights for designing future multifunctional metal complexes with enhanced metal-metal interactions.</p>

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Synthesis and Characterization of Novel Ruthenium(II) and Osmium(II) Monodentate Macrocyclic Complexes with Disulfide Linkage

  • 期刊论文

  • 发表日期：

    2025年11月1日

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  • J. Kong,
  • X. Bao

摘要

Abstract

A series of macrocyclic ligands featuring pyridyl functionalization and a disulfide linkage, along with their corresponding ruthenium(II) and osmium(II) complexes, were synthesized and characterized. The monodentate complexes were investigated in both the ‘open’ and ‘closed’ forms. These studies on electron/energy transfer through disulfide linkages provide critical insights for designing future multifunctional metal complexes with enhanced metal-metal interactions.