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Abstract <p>The mechanism of the cycloaddition reaction between singlet Me<sub>2</sub>Ge=Ge: and formaldehyde has been investigated with the MP2/6-311++G** method in this article, it could be predicted that the reaction has one dominant reaction pathway. The dominant reaction pathway consists of three elementary reactions: (1) the two reactants form a four-membered Ge-heterocyclic ring germylene; (2) the four-membered Ge-heterocyclic ring germylene further reacts with formaldehyde to form an intermediate; (3) the intermediate isomerizes to a spiro-Ge-heterocyclic ring compound via a transition state.</p>

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Features of Cycloaddition Reaction Between Me2Ge=Ge: and Formaldehyde

  • 期刊论文

  • 发表日期：

    2025年3月27日

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  • Jingsong Gu,
  • Huilian Xu,
  • Xiuhui Lu

摘要

Abstract

The mechanism of the cycloaddition reaction between singlet Me2Ge=Ge: and formaldehyde has been investigated with the MP2/6-311++G** method in this article, it could be predicted that the reaction has one dominant reaction pathway. The dominant reaction pathway consists of three elementary reactions: (1) the two reactants form a four-membered Ge-heterocyclic ring germylene; (2) the four-membered Ge-heterocyclic ring germylene further reacts with formaldehyde to form an intermediate; (3) the intermediate isomerizes to a spiro-Ge-heterocyclic ring compound via a transition state.