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Abstract <p>The reaction of 3,3-bis(3,5-dimethylpyrazol-1-yl)-1-phenylpropan-1-one (L) with cobalt(II) chloride and copper(II) chloride yielded neutral, isostructural heteroligand complexes [LMCl<sub>2</sub>] with M = Co for <b>I</b> and M = Cu for <b>II</b>. Their structures were determined by direct X-ray diffraction methods (CCDC nos.&#xa0;2478389 for <b>I</b>, 2478390 for <b>II</b>). In both complexes, the metal center has a tetrahedral coordination environment, and L coordinates to the metal ion in a bidentate manner.</p>

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Heteroligand Co(II) and Cu(II) Complexes with 3,3-Bis(3,5-dimethylpyrazol-1-yl)-1-phenylpropan-1-one: Synthesis and Crystal Structure

  • 期刊论文

  • 发表日期：

    2025年10月1日

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  • M. D. Gotsko,
  • N. A. Korobeinikov,
  • S. S. Opanasyuk,
  • S. A. Adonin

摘要

Abstract

The reaction of 3,3-bis(3,5-dimethylpyrazol-1-yl)-1-phenylpropan-1-one (L) with cobalt(II) chloride and copper(II) chloride yielded neutral, isostructural heteroligand complexes [LMCl2] with M = Co for I and M = Cu for II. Their structures were determined by direct X-ray diffraction methods (CCDC nos. 2478389 for I, 2478390 for II). In both complexes, the metal center has a tetrahedral coordination environment, and L coordinates to the metal ion in a bidentate manner.