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Abstract <p>The heteroleptic metal-organic frameworks {[Na(μ<sub>2</sub>-DMF)(HBpdc-I<sub>2</sub>)]}<sub><i>n</i></sub> (<b>I</b>) and {[Ca(DMF)<sub>2</sub>(Bpdc-I<sub>2</sub>)]} (<b>II</b>) were obtained by the reaction of sodium (NaOH) and calcium hydroxides (Ca(OH)<sub>2</sub>), respectively, with 2,2'-diiodobiphenyl-4,4'-dicarboxylic acid (H<sub>2</sub>(Bpdc-I<sub>2</sub>)) in <i>N</i>,<i>N</i>-dimethylformamide (DMF). The product structures were determined by X-ray diffraction. The compounds had two- and three-dimensional structures, respectively. A halogen bond was detected in <b>I</b> between the neighboring Bdc-I<sub>2</sub> ligands.</p>

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Structure of Sodium and Calcium Metal-Organic Frameworks with 2,2'-Diiodobiphenyl-4,4'-dicarboxylic Acid Anions

  • 期刊论文

  • 发表日期：

    2025年4月1日

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  • M. A. Bondarenko,
  • N. A. Korobeinikov,
  • A. S. Zaguzin,
  • R. V. Red’kin,
  • E. A. Pilyukova,
  • A. V. Zaitsev,
  • S. A. Adonin

摘要

Abstract

The heteroleptic metal-organic frameworks {[Na(μ2-DMF)(HBpdc-I2)]}n (I) and {[Ca(DMF)2(Bpdc-I2)]} (II) were obtained by the reaction of sodium (NaOH) and calcium hydroxides (Ca(OH)2), respectively, with 2,2'-diiodobiphenyl-4,4'-dicarboxylic acid (H2(Bpdc-I2)) in N,N-dimethylformamide (DMF). The product structures were determined by X-ray diffraction. The compounds had two- and three-dimensional structures, respectively. A halogen bond was detected in I between the neighboring Bdc-I2 ligands.