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Abstract <p>Six coordination compounds [UO<sub>2</sub>(L)<sub>2</sub>(NO<sub>3</sub>)<sub>2</sub>] were prepared by the reaction of UO<sub>2</sub>(NO<sub>3</sub>)<sub>2</sub> with amide L (L = acetamide, <i>N</i>,<i>N</i>-dimethylacetamide, propanamide, valeramide, benzamide, <i>N</i>-methylurea) in water. The composition and the structure of the products were established by elemental analysis, IR spectroscopy, and powder and single-crystal X-ray diffraction. The molecular structure and the assignment of absorption bands for the obtained compounds were confirmed by quantum chemical calculations.</p>

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Coordination Compounds of Uranyl Nitrate with Some Amide Ligands

  • 期刊论文

  • 发表日期：

    2025年1月1日

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  • M. S. Polukhin,
  • E. V. Savinkina,
  • I. A. Karavaev,
  • P. V. Akulinin,
  • G. A. Buzanov,
  • A. S. Kubasov,
  • M. S. Grigor’ev,
  • S. B. Strashnova

摘要

Abstract

Six coordination compounds [UO2(L)2(NO3)2] were prepared by the reaction of UO2(NO3)2 with amide L (L = acetamide, N,N-dimethylacetamide, propanamide, valeramide, benzamide, N-methylurea) in water. The composition and the structure of the products were established by elemental analysis, IR spectroscopy, and powder and single-crystal X-ray diffraction. The molecular structure and the assignment of absorption bands for the obtained compounds were confirmed by quantum chemical calculations.