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Abstract <p>A comprehensive study of the supramolecular organization of floating layers and Langmuir–Schaefer films of the heteronuclear complex “phthalocyanine-O-subphthalocyanine” is reported. The&#xa0;molecular packing of the studied compound in monolayer structures on a water surface was simulated, and the unit-cell parameters of the monolayer were calculated. Using grazing-incidence X-ray diffraction, X-ray standing-wave technique, and Brewster angle microscopy data, it was shown that this compound forms stable and uniform X-ray amorphous layers with edge-on molecular packing at the air/water interface. The&#xa0;obtained results open the possibility of effectively using thin-film structures based on the obtained Langmuir layers in nanoelectronics.</p>

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Supramolecular Organization of Floating Layers and Thin-Film Materials of the Heteronuclear Complex “Phthalocyane-O-Subphthalocyanine”

  • 期刊论文

  • 发表日期：

    2026年2月1日

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  • A. V. Kazak,
  • M. A. Marchenkova,
  • I. V. Rykov,
  • A. V. Rogachev,
  • Yu. E. Bonushkin,
  • V. K. Nikolaev,
  • A. A. Skvortsov,
  • A. Yu. Tolbin

摘要

Abstract

A comprehensive study of the supramolecular organization of floating layers and Langmuir–Schaefer films of the heteronuclear complex “phthalocyanine-O-subphthalocyanine” is reported. The molecular packing of the studied compound in monolayer structures on a water surface was simulated, and the unit-cell parameters of the monolayer were calculated. Using grazing-incidence X-ray diffraction, X-ray standing-wave technique, and Brewster angle microscopy data, it was shown that this compound forms stable and uniform X-ray amorphous layers with edge-on molecular packing at the air/water interface. The obtained results open the possibility of effectively using thin-film structures based on the obtained Langmuir layers in nanoelectronics.