Scholarlink

Abstract <p>A representation of liquid water as a real gas is used to modify the van der Waals equation of state for describing isotherms, isochores, and isobars of liquid water in wide ranges of pressure and temperature. The new thermal equation allows the standard transition to thermodynamics while reproducing internal energy <i>U</i>, free energy <i>F</i>, heat capacity <i>C</i><sub><i>V</i></sub>, and entropy <i>S</i>.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Modifying the van der Waals Equation to Describe the Thermodynamic Properties of Liquid Water

  • 期刊论文

  • 发表日期：

    2025年1月1日

查看全文
  • A. A. Volkov,
  • S. V. Chuchupal

摘要

Abstract

A representation of liquid water as a real gas is used to modify the van der Waals equation of state for describing isotherms, isochores, and isobars of liquid water in wide ranges of pressure and temperature. The new thermal equation allows the standard transition to thermodynamics while reproducing internal energy U, free energy F, heat capacity CV, and entropy S.