Abstract <p>This review is devoted to the examination of modern literature on aluminum batteries developed in recent years, which have already reached the stage of industrial production. Currently, lithium-ion batteries dominate the market. However, they have serious drawbacks: they are explosive and fire hazardous and also contain rare/expensive components (lithium, cobalt, nickel, electrolyte). Aluminum-ion batteries have advantages over lithium-ion batteries, namely: aluminum is cheap because it is the most widespread metal in the Earth’s crust; aluminum batteries are fire- and explosion-proof. As a result of comparing the “specific energy–specific power” combination for different types of aluminum-ion batteries, it is found that the most favorable combination of specific energy (247 W h/kg) and specific power (44.5 kW/kg) is shown by aluminum-ion batteries consisting of a graphite cathode etched with alkali, an aluminum anode, and an aluminum-chloride-based electrolyte. The highest combinations of specific capacity and current density are demonstrated by aluminum-ion batteries with CoSe cathode: 427 mA h/g at 1 A/g, and those based on MoSe<sub>2</sub>: 753 mA h/g at 0.3 A/g. The highest specific energy (685 W h/kg) is achieved by aluminum-ion batteries with CoMnO-cathode. Aluminum-ion batteries are characterized by a very high charging rate: up to 10 000 C (the discharge time 0.35 s) and also very high cyclability—up to 30 000 cycles.</p>

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Aluminum Batteries—Promising Rechargeable Energy Storage Devices: A Review

  • Yu. M. Volfkovich,
  • M. V. Dmitrieva

摘要

Abstract

This review is devoted to the examination of modern literature on aluminum batteries developed in recent years, which have already reached the stage of industrial production. Currently, lithium-ion batteries dominate the market. However, they have serious drawbacks: they are explosive and fire hazardous and also contain rare/expensive components (lithium, cobalt, nickel, electrolyte). Aluminum-ion batteries have advantages over lithium-ion batteries, namely: aluminum is cheap because it is the most widespread metal in the Earth’s crust; aluminum batteries are fire- and explosion-proof. As a result of comparing the “specific energy–specific power” combination for different types of aluminum-ion batteries, it is found that the most favorable combination of specific energy (247 W h/kg) and specific power (44.5 kW/kg) is shown by aluminum-ion batteries consisting of a graphite cathode etched with alkali, an aluminum anode, and an aluminum-chloride-based electrolyte. The highest combinations of specific capacity and current density are demonstrated by aluminum-ion batteries with CoSe cathode: 427 mA h/g at 1 A/g, and those based on MoSe2: 753 mA h/g at 0.3 A/g. The highest specific energy (685 W h/kg) is achieved by aluminum-ion batteries with CoMnO-cathode. Aluminum-ion batteries are characterized by a very high charging rate: up to 10 000 C (the discharge time 0.35 s) and also very high cyclability—up to 30 000 cycles.