Abstract <p>A crystalline sample of 5-amino-1H-tetrazole synthesized by us was used. The enthalpies of solution of crystalline 5-amino-1H-tetrazole in an aqueous KOH solution at 298.15 K were measured by a direct calorimetric method. The equilibrium composition of the system, including the stepwise dissociation of 5-amino-1H-tetrazole and water dissociation, was calculated using the KEV program. The standard enthalpies of formation of 5-amino-1H-tetrazole and its dissociation products in aqueous solution were calculated.</p>

错误:搜索内容不能为空,请输入英文关键词
错误:关键词超出字数限制,请精简
高级检索

Standard Enthalpies of Formation of 5-Amino-1H-Tetrazole and Its Dissociation Products in Aqueous Solution

  • O. N. Krutova,
  • V. S. Osokin,
  • M. I. Bazanov,
  • V. V. Chernikov,
  • P. D. Krutov,
  • R. A. Romanov

摘要

Abstract

A crystalline sample of 5-amino-1H-tetrazole synthesized by us was used. The enthalpies of solution of crystalline 5-amino-1H-tetrazole in an aqueous KOH solution at 298.15 K were measured by a direct calorimetric method. The equilibrium composition of the system, including the stepwise dissociation of 5-amino-1H-tetrazole and water dissociation, was calculated using the KEV program. The standard enthalpies of formation of 5-amino-1H-tetrazole and its dissociation products in aqueous solution were calculated.