Abstract <p>The authors study the solubility of tetra-4- and tetra-3-substituted copper phthalocyaninates with fragments of <i>ortho-</i>, <i>meta-</i>, or <i>pair-</i> phenol in the temperature range 288–318 K. The patterns of dissolution of compounds in chloroform depending on the position of the substituent located on the periphery of the molecule are discussed. Standard thermodynamic parameters of dissolution of synthesized metal complexes are calculated.</p>

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Solubility and Thermodynamic Characteristics of Dissolution of Copper Tetra-4/3-(methoxyphenoxy)phthalocyaninates in Chloroform

  • A. E. Rassolova,
  • G. R. Berezina,
  • V. E. Maizlish

摘要

Abstract

The authors study the solubility of tetra-4- and tetra-3-substituted copper phthalocyaninates with fragments of ortho-, meta-, or pair- phenol in the temperature range 288–318 K. The patterns of dissolution of compounds in chloroform depending on the position of the substituent located on the periphery of the molecule are discussed. Standard thermodynamic parameters of dissolution of synthesized metal complexes are calculated.