A Critical Review on Recent Progress in Refractory High Entropy Alloys: Mechanistic and Microstructural Aspects
摘要
Refractory high entropy alloys (RHEAs) have emerged as a promising class of materials, exhibiting exceptional high-temperature properties. This critical review aims to provide a comprehensive analysis of the recent progress in RHEAs, focusing on the intricate relationships between composition, processing, microstructure, and properties. A thorough examination of the thermodynamic and kinetic aspects of RHEAs reveals the pivotal role of configurational entropy, lattice distortion, and sluggish diffusion in governing their behavior. The review highlights the significance of single-phase solid solution formation, precipitation of secondary phases, and grain refinement in dictating the microstructural evolution of RHEAs. Recent advancements in RHEAs, including the development of novel alloy systems, innovative processing techniques, and computational simulation approaches, are critically evaluated. The influence of alloying elements, processing routes, and heat treatments on the microstructure and properties of RHEAs is elucidated, shedding light on the complex interplay between these factors. Despite significant progress, challenges persist in optimizing the ductility, toughness, and scalability of RHEAs. By providing a critical and comprehensive analysis of the current state of RHEA research, this review aims to inspire new investigations and accelerate the development of these promising materials for high-temperature applications. The insights gained from this review will facilitate the design of RHEAs with tailored properties, paving the way for their widespread adoption in aerospace, energy, and industrial sectors.