Abstract <p>Platinum catalysts with the additives of vanadium and tin were synthesized and studied in the reaction of methylcyclohexane dehydrogenation to toluene. Experimental data were obtained for the process of methylcyclohexane dehydrogenation, which are consistent with the synergistic effect of vanadium addition to a platinum–alumina catalyst in hydrogenation and dehydrogenation reactions, as predicted by quantum-chemical calculations.</p>

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Methylcyclohexane Dehydrogenation on Platinum–Alumina Catalysts Promoted with Vanadium and Tin

  • A. D. Lozhkin,
  • N. S. Panina,
  • T. M. Buslaeva,
  • L. G. Bruk

摘要

Abstract

Platinum catalysts with the additives of vanadium and tin were synthesized and studied in the reaction of methylcyclohexane dehydrogenation to toluene. Experimental data were obtained for the process of methylcyclohexane dehydrogenation, which are consistent with the synergistic effect of vanadium addition to a platinum–alumina catalyst in hydrogenation and dehydrogenation reactions, as predicted by quantum-chemical calculations.