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Abstract <p>A new binuclear <InlineEquation ID="IEq1"> <EquationSource Format="TEX">$\{\text{Mn}_{2}^{\text{III}}\}$</EquationSource> </InlineEquation> complex is synthesized. It is based on the salen-type ligand - an <i>o</i>-xylylenediamine derivative containing <i>o</i>-vanillin coordinating fragments. The structure of the obtained complex is analyzed by single crystal and powder X-ray diffraction, IR spectroscopy, mass spectrometry, and thermal gravimetric-differential scanning calorimetry. The band gap energy and localization of frontier orbitals are determined by quantum chemical calculations (DFT).</p>

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Synthesis and Structure of the New Binuclear Complex Based on the o-Xylylenediamine-Supported Salen-Type Ligand with o-Vanillin Moieties

  • 期刊论文

  • 发表日期：

    2026年7月30日

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  • I. D. Shutilov,
  • P. A. Volodin,
  • A. S. Ovsyannikov,
  • L. V. Frantsuzova,
  • P. V. Dorovatovskiy,
  • A. E. Vandyukov,
  • A. R. Khamatgalimov,
  • S. E. Solovieva,
  • I. S. Antipin

摘要

Abstract

A new binuclear $\{\text{Mn}_{2}^{\text{III}}\}$ complex is synthesized. It is based on the salen-type ligand - an o-xylylenediamine derivative containing o-vanillin coordinating fragments. The structure of the obtained complex is analyzed by single crystal and powder X-ray diffraction, IR spectroscopy, mass spectrometry, and thermal gravimetric-differential scanning calorimetry. The band gap energy and localization of frontier orbitals are determined by quantum chemical calculations (DFT).