Scholarlink

Abstract <p>We report the syntheses, structural and thermal analyses of four coordination complexes namely {[Cd(L1)<sub>2</sub>(NDC)]·4DMF}<sub><i>n</i></sub>·<b>1</b>, {[CuL2]·DMF}<sub><i>n</i></sub>·<b>2</b>, {[Zn(L3)<sub>0.5</sub>(DDN)]·DMF}<sub><i>n</i></sub>·<b>3</b> and {[Zn(L4)<sub>0.5</sub> (DDN)]·DMF·H<sub>2</sub>O}<sub><i>n</i></sub> <b>4</b>. Here, L1 is 2,2′-bis(pyridin-4-ylmethyl)-[5,5′-biisoindoline]-1,1′,3,3′-tetraone; L2 is 2,2′-(1,1′,3,3′-tetraoxo-[5,5′-biisoindoline]-2,2′-diyl)diacetic acid; L3 is 2,7-bis(pyridin-3-ylmethyl)benzo [<i>lmn</i>][3,8]phenanthroline-1,3,6,8(2<i>H</i>,7<i>H</i>)-tetraone; L4 is 2,7-bis(pyridin-4-ylmethyl)benzo[<i>lmn</i>][3,8] phenanthroline-1,3,6,8(2<i>H</i>,7<i>H</i>)-tetraone; DMF is N,N-dimethylformamide; H<sub>2</sub>NDC is 2,6-naphthalene dicarboxylic acid; and H<sub>2</sub>DDN is 6,6′-dithiodinicotinic acid. Complexes <b>1</b>, <b>3</b>, and <b>4</b> are three-dimensional, while complex&#xa0;<b>2</b> is two-dimensional. Powder X-ray diffraction indicates that complex&#xa0;<b>1</b> changes its structure upon desolvation but does not revert to its original form when exposed to DMF. Carbon dioxide (CO<sub>2</sub>) sorption studies on <b>1</b> indicate that the complex adsorbs minimal amounts of CO<sub>2</sub> at 273&#xa0;K.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Coordination Complexes of Cd(II), Cu(II), Zn(II), and Substituted Diimide Ligands: Syntheses, Structural Analyses and Gas Sorption Studies

  • 期刊论文

  • 发表日期：

    2026年4月1日

查看全文
  • R. Mahwasane,
  • L. Mbonzhe,
  • N. Chatterjee,
  • E. Batisai

摘要

Abstract

We report the syntheses, structural and thermal analyses of four coordination complexes namely {[Cd(L1)2(NDC)]·4DMF}n·1, {[CuL2]·DMF}n·2, {[Zn(L3)0.5(DDN)]·DMF}n·3 and {[Zn(L4)0.5 (DDN)]·DMF·H2O}n 4. Here, L1 is 2,2′-bis(pyridin-4-ylmethyl)-[5,5′-biisoindoline]-1,1′,3,3′-tetraone; L2 is 2,2′-(1,1′,3,3′-tetraoxo-[5,5′-biisoindoline]-2,2′-diyl)diacetic acid; L3 is 2,7-bis(pyridin-3-ylmethyl)benzo [lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone; L4 is 2,7-bis(pyridin-4-ylmethyl)benzo[lmn][3,8] phenanthroline-1,3,6,8(2H,7H)-tetraone; DMF is N,N-dimethylformamide; H2NDC is 2,6-naphthalene dicarboxylic acid; and H2DDN is 6,6′-dithiodinicotinic acid. Complexes 1, 3, and 4 are three-dimensional, while complex 2 is two-dimensional. Powder X-ray diffraction indicates that complex 1 changes its structure upon desolvation but does not revert to its original form when exposed to DMF. Carbon dioxide (CO2) sorption studies on 1 indicate that the complex adsorbs minimal amounts of CO2 at 273 K.