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Abstract <p>Dimeric cadmium complexes based on 1,2-bis-{(2,4,6-trimethylphenyl)}iminoacenaphthene (tmp-bian) are obtained. Their compositions are [{Cd(tmp-bian)Br}<sub>2</sub>(μ-Br)<sub>2</sub>] (<b>1</b>) and [{Cd(tmp-bian)I}<sub>2</sub>(μ-I)<sub>2</sub>] (<b>2</b>). The compounds synthesized are characterized by the elemental analysis, <sup>1</sup>H NMR and IR spectrometry. Molecular structures of <b>1</b> and <b>2</b> are determined by single crystal X-ray diffraction. The electrochemical properties of the compounds are studied by cyclic voltammetry.</p>

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Binuclear Cadmium(II) Complexes Based on 1,2-bis-{(2,4,6-trimethylphenyl)}Iminoacenaphthene: Synthesis, Structure, and Electrochemical Properties

  • 期刊论文

  • 发表日期：

    2026年4月1日

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  • E. V. Chekhov,
  • I. V. Bakaev,
  • V. I. Komlyagina,
  • A. A. Ulantikov,
  • N. F. Romashev,
  • A. L. Gushchin

摘要

Abstract

Dimeric cadmium complexes based on 1,2-bis-{(2,4,6-trimethylphenyl)}iminoacenaphthene (tmp-bian) are obtained. Their compositions are [{Cd(tmp-bian)Br}2(μ-Br)2] (1) and [{Cd(tmp-bian)I}2(μ-I)2] (2). The compounds synthesized are characterized by the elemental analysis, 1H NMR and IR spectrometry. Molecular structures of 1 and 2 are determined by single crystal X-ray diffraction. The electrochemical properties of the compounds are studied by cyclic voltammetry.