Abstract <p>Complexes {(3,5-MePy)<sub>2</sub>(CH<sub>2</sub>)<sub><i>n</i></sub>}<sub>3</sub>[Bi<sub>2</sub>Br<sub>9</sub>]<sub>2</sub> (<i>n</i>&#xa0;=&#xa0;2 (<b>1</b>), 5 (<b>2</b>)) are obtained by the reaction of bismuth oxide with salts of various doubly charged cations based on 3,5-dimethylpyridine in concentrated HBr, and they are structurally characterized by X-ray diffraction. The features of intermolecular contacts in the crystal structure are considered.</p>

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Binuclear Bi(III) Bromide Complexes with 1,1′-(alkane-1,X-diyl)Bis(3,5-dimethyl)Pyridine Dications

  • I. A. Shentseva,
  • A. N. Usoltsev,
  • N. A. Korobeynikov,
  • M. N. Sokolov,
  • S. A. Adonin

摘要

Abstract

Complexes {(3,5-MePy)2(CH2)n}3[Bi2Br9]2 (n = 2 (1), 5 (2)) are obtained by the reaction of bismuth oxide with salts of various doubly charged cations based on 3,5-dimethylpyridine in concentrated HBr, and they are structurally characterized by X-ray diffraction. The features of intermolecular contacts in the crystal structure are considered.