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Abstract <p>The reaction of zinc nitrate with 3,6-di-4-pyridyl-1,2,4,5-tetrazine (4-DPT), 3,6-di-3-pyridyl-1,2,4,5-tetrazine (3-DPT), and <i>trans</i>-β-hydromuconic acid (H<sub>2</sub>TBHMA) yields new MOFs of the following compositions: [Zn(3-DPT)(DMF)(NO<sub>3</sub>)<sub>2</sub>] (<b>1</b>), [Zn(3-DPT)(TBHMA)]·(MeOH) (<b>2</b>·MeOH), and [Zn<sub>2</sub>(4-DPT)<sub>2</sub>(TBHMA)(NO<sub>3</sub>)<sub>2</sub>]·2MeOH (<b>3</b>·2MeOH). Structures of the compounds are studied by single crystal X-ray diffraction (CIF file CCDC Nos.&#xa0;2450436(<b>1</b>), 2450437 (<b>2</b>), 2450438 (<b>3</b>)).</p>

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Metal-Organic Frameworks of Zinc with Tetrazine and Carboxylate Ligands

  • 期刊论文

  • 发表日期：

    2025年9月1日

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  • D. S. Kolevatov,
  • N. O. Druzhkov,
  • I. A. Yakushev,
  • P. V. Dorovatovskii,
  • A. V. Piskunov

摘要

Abstract

The reaction of zinc nitrate with 3,6-di-4-pyridyl-1,2,4,5-tetrazine (4-DPT), 3,6-di-3-pyridyl-1,2,4,5-tetrazine (3-DPT), and trans-β-hydromuconic acid (H2TBHMA) yields new MOFs of the following compositions: [Zn(3-DPT)(DMF)(NO3)2] (1), [Zn(3-DPT)(TBHMA)]·(MeOH) (2·MeOH), and [Zn2(4-DPT)2(TBHMA)(NO3)2]·2MeOH (3·2MeOH). Structures of the compounds are studied by single crystal X-ray diffraction (CIF file CCDC Nos. 2450436(1), 2450437 (2), 2450438 (3)).