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Abstract <p>A 3D metal–organic framework [Mn<sub>4</sub>(2,5-I-bdc)<sub>4</sub>(DMF)<sub>4</sub>]·0.5DMF (<b>1</b>) is prepared by the reaction of MnCl<sub>2</sub>·4H<sub>2</sub>O with H<sub>2</sub>(2,5-I-bdc) (2,5-diiodoterephthalic acid) and is structurally characterized. Thermal stability and luminescent properties (blue emission) of <b>1</b> are studied.</p>

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3D Mn(II) Metal–Organic Framework Based on 2,5-Diiodoterephthalate

  • 期刊论文

  • 发表日期：

    2025年9月1日

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  • M. A. Bondarenko,
  • A. S. Zaguzin,
  • N. A. Korobeinikov,
  • R. V. Redkin,
  • E. A. Pilyukova,
  • A. V. Zaitsev,
  • I. V. Korolkov,
  • M. I. Rakhmanova,
  • S. A. Adonin

摘要

Abstract

A 3D metal–organic framework [Mn4(2,5-I-bdc)4(DMF)4]·0.5DMF (1) is prepared by the reaction of MnCl2·4H2O with H2(2,5-I-bdc) (2,5-diiodoterephthalic acid) and is structurally characterized. Thermal stability and luminescent properties (blue emission) of 1 are studied.