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Abstract <p>Two new molybdenum cluster complexes Na<sub>2</sub>[Mo<sub>6</sub>I<sub>8</sub>L<sub>6</sub>] (L&#xa0;=&#xa0;–CH<sub>2</sub>=CH–COO<sup>–</sup> (acrylate, Acr<sup>–</sup>) and –CH<sub>2</sub>=C(CH<sub>3</sub>)–COO<sup>–</sup> (methacrylate, MAcr<sup>–</sup>)) are prepared and studied. The complexes are prepared by solvothermal synthesis in methanol from Na<sub>2</sub>[Mo<sub>6</sub>I<sub>8</sub>(OMe)<sub>6</sub>] in the presence of small excess of the corresponding organic acid. As a result, XRD-quality single crystals of Na<sub>2</sub>[Mo<sub>6</sub>I<sub>8</sub>L<sub>6</sub>]·2MeOH are formed. The composition and purity of the phases are confirmed by the CHN elemental analysis, energy dispersion analysis, IR spectroscopy, and powder XRD. Photoluminescent properties of both complexes in the solid state and in a dimethylformamide solution are studied.</p>

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Sodium Salts of Octahedral Molybdenum Complexes with Acrylate and Methacrylate Ligands

  • 期刊论文

  • 发表日期：

    2025年7月1日

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  • N. A. Vorotnikova,
  • A. S. Berezin,
  • N. V. Kuratieva,
  • M. A. Shestopalov,
  • Y. A. Vorotnikov

摘要

Abstract

Two new molybdenum cluster complexes Na2[Mo6I8L6] (L = –CH2=CH–COO– (acrylate, Acr–) and –CH2=C(CH3)–COO– (methacrylate, MAcr–)) are prepared and studied. The complexes are prepared by solvothermal synthesis in methanol from Na2[Mo6I8(OMe)6] in the presence of small excess of the corresponding organic acid. As a result, XRD-quality single crystals of Na2[Mo6I8L6]·2MeOH are formed. The composition and purity of the phases are confirmed by the CHN elemental analysis, energy dispersion analysis, IR spectroscopy, and powder XRD. Photoluminescent properties of both complexes in the solid state and in a dimethylformamide solution are studied.