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Abstract <p>The [Pd(phen)(Ph-mhan)](OTf) coordination compound is prepared by the interaction of [Pd(phen)Cl<sub>2</sub>] with 2-monophenylhydrazinoacenaphthene-1-one (Ph-mhan) in the presence of silver triflate. During the reaction, Ph-mhan is deprotonated and is coordinated to the Pd(II) ion as an anion. The obtained compound is characterized by elemental analysis, IR, and <sup>1</sup>H NMR spectroscopy; its crystal structure is determined by XRD; electrochemical and optical properties are studied by cyclic voltammetry and electron absorption spectroscopy, respectively.</p>

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Palladium(II) Coordination Compound Based on 2-Monophenylhydrazinoacenaphthene-1-One: Synthesis, Structure, and Properties

  • 期刊论文

  • 发表日期：

    2025年4月1日

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  • A. K. Gukova,
  • V. I. Komlyagina,
  • I. V. Bakaev,
  • E. V. Chekhov,
  • I. S. Fomenko,
  • N. F. Romashev,
  • A. L. Gushchin

摘要

Abstract

The [Pd(phen)(Ph-mhan)](OTf) coordination compound is prepared by the interaction of [Pd(phen)Cl2] with 2-monophenylhydrazinoacenaphthene-1-one (Ph-mhan) in the presence of silver triflate. During the reaction, Ph-mhan is deprotonated and is coordinated to the Pd(II) ion as an anion. The obtained compound is characterized by elemental analysis, IR, and 1H NMR spectroscopy; its crystal structure is determined by XRD; electrochemical and optical properties are studied by cyclic voltammetry and electron absorption spectroscopy, respectively.