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Abstract <p>Single crystals of complexes between bidentate Lewis acids R[OB(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>]<sub>2</sub> (R&#xa0;=&#xa0;C<sub>2</sub>H<sub>4</sub>, <i>p</i>-C<sub>6</sub>H<sub>4</sub>) and pyrazine (pyz) are obtained for the first time and characterized by the single crystal X-ray diffraction analysis. Despite the possible formation of polymeric compounds, there is the monodentate coordination of pyrazine molecules to each of boron atoms of bidentate acid.</p>

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Synthesis and Structures of Bidentate Lewis Acid Complexes R[OB(C6F5)2]2 (R = C2H4, p-C6H4) with Pyrazine

  • 期刊论文

  • 发表日期：

    2025年2月1日

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  • P. I. Kudina,
  • M. A. Kryukova,
  • I. V. Kazakov

摘要

Abstract

Single crystals of complexes between bidentate Lewis acids R[OB(C6F5)2]2 (R = C2H4, p-C6H4) and pyrazine (pyz) are obtained for the first time and characterized by the single crystal X-ray diffraction analysis. Despite the possible formation of polymeric compounds, there is the monodentate coordination of pyrazine molecules to each of boron atoms of bidentate acid.